Anilinium chloride as a model for the transition state for benzyl chloride solvolysis
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چکیده
منابع مشابه
4-(Cyanomethyl)anilinium chloride
The crystal structure of the title compound, C(8)H(9)N(2) (+)·Cl(-), is stabilized by N-H⋯Cl hydrogen bonds.
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In the crystal of the title compound, C(8)H(10)NO(2) (+)·Cl(-), alternating layers of hydro-phobic and hydro-philic zones stack along the c axis. The chloride anions are sandwiched between the 4-(carboxy-meth-yl)anilinium layers, forming inter-molecular O-H⋯Cl and N-H⋯Cl hydrogen bonds with the ammonium and carboxyl groups of the cations. In addition, inter-molecular N-H⋯O and weak C-H⋯O and C-...
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In the cation of the title compound, C(14)H(13)N(2)O(+)·Cl(-), the two benzene rings are roughly parallel and are twisted slightly from each other by a dihedral angle of only 2.87 (1)°. In the crystal, weak inter-molecular N-H⋯Cl and O-H⋯Cl hydrogen bonds link the cations and anions into chains extended along the b axis.
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N-Benzyl-N-methylmorpholinium chloride
In the title compound, C(12)H(18)NO(+)·Cl(-), the cations and anions are inter-connected by weak C-H⋯Cl hydrogen bonds. The morpholine ring system adopts a chair conformation.
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1969
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v69-237